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Doctorate
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GRADUATE INSTITUTE of NATURAL and APPLIED SCIENCES / DEPARTMENT of CHEMISTRY / Doctorate
Katalog Ana Sayfa
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KIML7811Cobalt Phthalcyanines and Cat. Propert.3+0+0ECTS:7.5
Year / SemesterSpring Semester
Level of CourseThird Cycle
Status Elective
DepartmentDEPARTMENT of CHEMISTRY
Prerequisites and co-requisitesNone
Mode of Delivery
Contact Hours14 weeks - 3 hours of lectures per week
LecturerProf. Dr. Ece Tuğba SAKA
Co-LecturerNone
Language of instructionTurkish
Professional practise ( internship ) None
 
The aim of the course:
The purpose of this course; Physical and chemical properties of cobalt metal as central atom, cobalt phthalocyanines and their formation reactions, physical, chemical, spectral and electrochemical properties of cobalt phthalocyanines, aerobic oxidation reactions catalyzed by homogeneous cobalt phthalocyanine, aerobic oxidation mechanisms of olefins catalyzed by cobalt phthalocyanine, aerobic oxidation of phenolic compounds role of cobalt phthalocyanines, parameters affecting aerobic oxidation of phenolic compounds, reaction mechanisms of cobalt phthalocyanine catalyst for some phenol compounds, effect of cobalt catalysts in aerobic oxidation of sulfur compounds, reduction reactions containing homogeneous cobalt catalyst and proposed reaction mechanisms, applications of cobalt phthalocyanines in industry as catalysts, Recent developments in homogeneous cobalt phthalocyanine
 
Programme OutcomesCTPOTOA
Upon successful completion of the course, the students will be able to :
PO - 1 : Physical and chemical properties of cobalt metal as central atom2,31,2,3,
PO - 2 : their formation reactions, physical, chemical, spectral and electrochemical properties of cobalt phthalocyanines2,31,2,3,
PO - 3 : aerobic oxidation reactions catalyzed by homogeneous cobalt phthalocyanine2,31,2,3,
PO - 4 : aerobic oxidation mechanisms of olefins catalyzed by cobalt phthalocyanine2,31,2,3,
PO - 5 : aerobic oxidation of phenolic compounds role of cobalt phthalocyanines2,31,2,3,
PO - 6 : parameters affecting aerobic oxidation of phenolic compounds2,31,2,3,
PO - 7 : reaction mechanisms of cobalt phthalocyanine catalyst for some phenol compounds2,31,2,3,
PO - 8 : effect of cobalt catalysts in aerobic oxidation of sulfur compounds2,31,2,3,
PO - 9 : proposed reaction mechanisms, applications of cobalt phthalocyanines in industry as catalysts,2,31,2,3,
PO - 10 : Recent developments in homogeneous cobalt phthalocyanine 2,31,2,3,
CTPO : Contribution to programme outcomes, TOA :Type of assessment (1: written exam, 2: Oral exam, 3: Homework assignment, 4: Laboratory exercise/exam, 5: Seminar / presentation, 6: Term paper), PO : Learning Outcome

 
Contents of the Course
Physical and chemical properties of cobalt metal as central atom, cobalt phthalocyanines and their formation reactions, physical, chemical, spectral and electrochemical properties of cobalt phthalocyanines, aerobic oxidation reactions catalyzed by homogeneous cobalt phthalocyanine, aerobic oxidation mechanisms of olefins catalyzed by cobalt phthalocyanine, aerobic oxidation of phenolic compounds role of cobalt phthalocyanines, parameters affecting aerobic oxidation of phenolic compounds, reaction mechanisms of cobalt phthalocyanine catalyst for some phenol compounds, effect of cobalt catalysts in aerobic oxidation of sulfur compounds, reduction reactions containing homogeneous cobalt catalyst and proposed reaction mechanisms, applications of cobalt phthalocyanines in industry as catalysts, Recent developments in homogeneous cobalt phthalocyanine
 
Course Syllabus
 WeekSubjectRelated Notes / Files
 Week 1Physical and chemical properties of cobalt metal as central atom
 Week 2cobalt phthalocyanines and their formation reactions
 Week 3their formation reactions, physical, chemical, spectral and electrochemical properties of cobalt phthalocyanines
 Week 4aerobic oxidation reactions catalyzed by homogeneous cobalt phthalocyanine
 Week 5aerobic oxidation mechanisms of olefins catalyzed by cobalt phthalocyanine
 Week 6aerobic oxidation of phenolic compounds role of cobalt phthalocyanines
 Week 7parameters affecting aerobic oxidation of phenolic compounds, reaction
 Week 8reaction mechanisms of cobalt phthalocyanine catalyst for some phenol compounds
 Week 9effect of cobalt catalysts in aerobic oxidation of sulfur compounds
 Week 10reduction reactions containing homogeneous cobalt catalyst and proposed reaction mechanisms
 Week 11applications of cobalt phthalocyanines in industry as catalysts,
 Week 12Recent developments in homogeneous cobalt phthalocyanine
 Week 13exam
 Week 14Offer cobalt phthalocyanine containing catalytic system
 Week 15Offer cobalt phthalocyanine containing catalytic system
 Week 16exam
 
Textbook / Material
1Metaller Kimyası, Ramazan Tezcan, Habibe Tezcan, Nobel Yayıncılık, 288 sayfa, 2007.
2Phthalocyanine:Properties and Applications, CC Leznoff, ABP Lever, VCH Publishers, 314 sayfa, 1989.
 
Recommended Reading
1Photosensitizers in Medicine, Environment and Security, T. Nyokong ve V. Ahsen, Springer, 619 pages, 2012.
2Phthalocyanine Metal Complexes in catalysis, A. B. Sorokin, Chemical Reviews, 2013, 113, 8152-8191.
 
Method of Assessment
Type of assessmentWeek NoDate

Duration (hours)Weight (%)
Mid-term exam 9
 22/04/2019 2 30
In-term studies (second mid-term exam) 1
2
3
4
5
6
7
8		 3
Oral exam 10
11		 2 10
Presentation 12
13
14		 3 5
Homework/Assignment/Term-paper 15
16		 3 5
End-of-term exam 17 2 50
 
Student Work Load and its Distribution
Type of workDuration (hours pw)

No of weeks / Number of activity

Hours in total per term
Yüz yüze eğitim 3 13 39
Arasınav 2 1 2
Uygulama 3 12 36
Ödev 3 4 12
Kısa sınav 3 2 6
Dönem sonu sınavı için hazırlık 3 10 30
Dönem sonu sınavı 2 1 2
Total work load127