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| KIM7171 | Metal-to-Metal Bonds and Metal Atom Clusters | 3+0+0 | ECTS:7.5 | | Year / Semester | Spring Semester | | Level of Course | Third Cycle | | Status | Elective | | Department | DEPARTMENT of CHEMISTRY | | Prerequisites and co-requisites | None | | Mode of Delivery | Face to face | | Contact Hours | 14 weeks - 3 hours of lectures per week | | Lecturer | -- | | Co-Lecturer | non | | Language of instruction | Turkish | | Professional practise ( internship ) | None | | | | The aim of the course: | | The main goal of the Course is to give basic information about clusters containin transition metals with differint organic ligands and to explain structure, bonding and the methods of synthesi of some clusters. |
| Programme Outcomes | CTPO | TOA | | Upon successful completion of the course, the students will be able to : | | | | PO - 1 : | Students should have gained skills to differ a cluster from a non-cluster compund. | 1,2,3 | 1 | | PO - 2 : | Students shoulh have gained skills to explain the structure, bonding and electron counting in a cluster. | 1,2,3 | 1 | | PO - 3 : | Students should have learned the synthesis method of some clusters and the nature of metal-metal bonding. | 1,2,3 | 1 | | CTPO : Contribution to programme outcomes, TOA :Type of assessment (1: written exam, 2: Oral exam, 3: Homework assignment, 4: Laboratory exercise/exam, 5: Seminar / presentation, 6: Term paper), PO : Learning Outcome | | |
| Introduction, Metal Carbonyl Clusters, Anionic and Hydrido Clusters, Triatomic Clusters, Four-atom Clusters, Isoelectronic and Isolobal Relationships, High-Nuclearity Carbonyl Clusters, Methods of Synthesis, Hetero atoms in Metal Atom Clusters, Carbide-Containing Clusters, Nitride- Containing Clusters, Electron Counting Schemens for HNCCs, the Capping Rulu, HNCCs of Some Transition Metals, Compounds with M-M Multiple Bonds |
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| Course Syllabus | | Week | Subject | Related Notes / Files | | Week 1 | General Information About Clusters | | | Week 2 | Metal Carbonyl Clusters | | | Week 3 | Metal Carbonyl Clusters | | | Week 4 | Clusters Containing Three Metal atoms | | | Week 5 | Clusters Containing Four Metal Atoms | | | Week 6 | Isoelectronic and Isolobal Relation | | | Week 7 | Isoelectronic and Isolobal Relation | | | Week 8 | Mid-term exam | | | Week 9 | Isoelectronic and Isolobal Relation | | | Week 10 | Isoelectronic and Isolobal Relation | | | Week 11 | Synthesis Methods of Clusters | | | Week 12 | Hetero Atom in Metal Atom Clusters | | | Week 13 | Electron Counting Schemes for HNCCs | | | Week 14 | Some Clusters Containing Poly Transition Metals | | | Week 15 | Compunds with M-M Bonds | | | Week 16 | End-of-term exam | | | |
| 1 | Cotten, F.A., Wilkinson, G. 1988; Advanced Inorganic Chemistry, John Wiley and Sons, New York | | | |
| 1 | Huheey, J.E. 1978; Inorganic Chemşstry, Harper and Row, New York | | | |
| Method of Assessment | | Type of assessment | Week No | Date | Duration (hours) | Weight (%) | | Mid-term exam | 8 | 10/11/2009 | 120 | 30 | | In-term studies (second mid-term exam) | 13 | 14/12/2009 | 120 | 20 | | End-of-term exam | 16 | 05/01/2010 | 120 | 50 | | |
| Student Work Load and its Distribution | | Type of work | Duration (hours pw) | No of weeks / Number of activity | Hours in total per term | | Yüz yüze eğitim | 3 | 14 | 42 | | Sınıf dışı çalışma | 5 | 14 | 70 | | Arasınav için hazırlık | 4 | 6 | 24 | | Arasınav | 2 | 1 | 2 | | Ödev | 4 | 9 | 36 | | Dönem sonu sınavı için hazırlık | 4 | 6 | 24 | | Dönem sonu sınavı | 2 | 1 | 2 | | Total work load | | | 200 |
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