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| KIML7810 | Homogeneous Catalysis and Applications | 3+0+0 | ECTS:7.5 | | Year / Semester | Spring Semester | | Level of Course | Third Cycle | | Status | Elective | | Department | DEPARTMENT of CHEMISTRY | | Prerequisites and co-requisites | None | | Mode of Delivery | | | Contact Hours | 14 weeks - 3 hours of lectures per week | | Lecturer | Prof. Dr. Ece Tuğba SAKA | | Co-Lecturer | | | Language of instruction | Turkish | | Professional practise ( internship ) | None | | | | The aim of the course: | | The aim of lesson; To define the catalyst in general terms, to examine the metal effect for the targeted catalyst design, to determine the activity of the catalyst according to the properties of the central metal atom, to define the catalysis systems, to determine the advantages and disadvantages, to determine the catalytic reaction mechanisms, ligand coordination and separation, intercalation and elimination, coordinate Nucleophilic attack on ligands, oxidation and reduction, oxidant addition and reductive elimination, some organometallic and coordination compounds to examine their use in homogeneous catalysis systems, hydrogenation of alkenes, hydroformylation, Monsanto acetic acid synthesis, Wacker oxidation of alkenes, polymerization of alkenes reactions in the presence of catalysts and evaluation the results in the presence of studies in the literature. |
| Programme Outcomes | CTPO | TOA | | Upon successful completion of the course, the students will be able to : | | | | PO - 1 : | They can easily define catalyst and catalysis | 1,2,3 | | | PO - 2 : | They can learn the effect of metal atom in designing catalyst | 1,2,3 | | | PO - 3 : | They can learn the properties of metal atoms in used | 1,2,3 | | | PO - 4 : | They can learn to define catalyst systems, determine the adv and disadv. | 1,2,3 | | | PO - 5 : | They can learn catalytic reaction mechanisms, ligand coordination and separation | 1,2,3 | | | PO - 6 : | They can learn insertion and elimination, nucleophilic attack reactions to coordinated ligands | 1,2,3 | | | PO - 7 : | They learns oxidation and reduction, oxidative addition and reductive elimination reactions. | 1,2,3 | | | PO - 8 : | They can learns to examine the use of some organometallic and coordination compounds in homogeneous catalysis systems. | 1,2,3 | | | PO - 9 : | They can learns hydrogenation of alkenes, hydroformylation, Monsanto acetic acid synthesis reactions. | 1,2,3 | | | PO - 10 : | They can learns Wacker oxidation of alkenes, polymerization reaction of alkenes. | 1,2,3 | | | CTPO : Contribution to programme outcomes, TOA :Type of assessment (1: written exam, 2: Oral exam, 3: Homework assignment, 4: Laboratory exercise/exam, 5: Seminar / presentation, 6: Term paper), PO : Learning Outcome | | |
| Definition of catalysis and catalysts, effects of central metal atom in the designation of catalyst, often used central metal atoms and their properties, identification of catalysis systems, determination of advantages and disadvantages, catalytic reaction mechanisms, ligand coordination and disassociation, joining and disassociation, nucleophilic attack to coordinative ligands, oxidation and reduction , Oxidative addition and reduction elimination, investigation of the use of some organometallic and coordination compounds in homogeneous catalysis systems, hydrogenation of alkenes, hydroformylation, Monsanto acetic acid synthesis, Wacker oxidation of alkenes, polymerization of alkenes |
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| Course Syllabus | | Week | Subject | Related Notes / Files | | Week 1 | Definition of catalyst and catalysis | | | Week 2 | Metal atom effect in designing catalyst | | | Week 3 | Commonly used central metal atom and their properties | | | Week 4 | Definition of catalytical systems, determination of adv and disadv | | | Week 5 | investigation of catalytic reaction mechanisms, ligand coordination and cleavage reactions | | | Week 6 | Investigation of intercalation and elimination, nucleophilic attack reactions to coordinated ligands | | | Week 7 | oxidation and reduction, oxidative addition and reductive elimination, investigation of their reactions | | | Week 8 | Investigation of the use of some organometallic and coordination compounds in homogeneous catalysis systems. | | | Week 9 | hydrogenation of alkenes | | | Week 10 | Hydroformilation reactions | | | Week 11 | Monsanto Acetic Acid synthesis | | | Week 12 | Wacker oxidation of alkenes | | | Week 13 | polymerization of alkenes | | | Week 14 | Other reactions of alkenes | | | Week 15 | Evaluation of studies in literature | | | Week 16 | Designing of a sample work | | | |
| 1 | Environmental Catalysis, Vicki H. Grassian, Taylor&Francis 2005 | | | |
| 1 | Catalysis without precious metals, R. Morris Bullock, Wiley-VCH Verlag GMBH%Co, KGaA, 2010 | | | 2 | Catalysis, Specialist Periodical Reports, J.J. Spivey and K.M. Dooley, Volume 21, 2009. | | | |
| Method of Assessment | | Type of assessment | Week No | Date | Duration (hours) | Weight (%) | | Mid-term exam | 9 | 20/04/2022 | 2 | 30 | | In-term studies (second mid-term exam) | 1,2,3,4,5,6,7,8 | | 3 | 5 | | Oral exam | 10,11 | | 2 | 5 | | Presentation | 12,13,14 | | 3 | 5 | | Homework/Assignment/Term-paper | 15,16 | | 3 | 5 | | End-of-term exam | 17 | | 2 | 50 | | |
| Student Work Load and its Distribution | | Type of work | Duration (hours pw) | No of weeks / Number of activity | Hours in total per term | | Yüz yüze eğitim | 3 | 13 | 39 | | Arasınav | 2 | 1 | 2 | | Uygulama | 3 | 12 | 36 | | Ödev | 3 | 4 | 12 | | Kısa sınav | 3 | 2 | 6 | | Dönem sonu sınavı için hazırlık | 3 | 10 | 30 | | Dönem sonu sınavı | 2 | 1 | 2 | | Total work load | | | 127 |
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