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| KIM 142 | Physical Chemistry | 3+0+0 | ECTS:4 | | Year / Semester | Spring Semester | | Level of Course | First Cycle | | Status | Compulsory | | Department | DEPARTMENT of METALLURGICAL and MATERIALS ENGINEERING | | Prerequisites and co-requisites | None | | Mode of Delivery | Face to face | | Contact Hours | 14 weeks - 3 hours of lectures per week | | Lecturer | Prof. Dr. Sedat KELEŞ | | Co-Lecturer | Prof. Dr. Rza Abbasoglu, Prof. Dr. Kamil KAYGUSUZ, Prof. Dr. Sevil Savaşkan YILMAZ, Asst. Prof. Dr. Selçuk BİLGEN, Lecturer Cüneyt VOLGA | | Language of instruction | Turkish | | Professional practise ( internship ) | None | | | | The aim of the course: | | The course aims to provide the students with a general knowledge on chemical kinetics, adsorption, solid state, electrochemical cell with industrial applications, chemical reaction mechanisms to learn how chemical reaction are performed, to teach them how to use rate laws of kinetics to explain the mechanism of the chemical reactions, to teach them how to use kinetic theory of the gases to explain the motion in the solids, liquids and gases |
| Learning Outcomes | CTPO | TOA | | Upon successful completion of the course, the students will be able to : | | | | LO - 1 : | know the structure of liquid and solids. | 2,3,4,6,7,8 | 1 | | LO - 2 : | describe thermodinamic laws and know calculation of rate constants. | 2,3,4,6,7,8 | 1 | | LO - 3 : | explaine electrochemical reactions and corrosion. | 2,3,4,6,7,8 | 1 | | LO - 4 : | know adsorption and its industrial applications. | 2,3,4,6,7,8 | 1 | | CTPO : Contribution to programme outcomes, TOA :Type of assessment (1: written exam, 2: Oral exam, 3: Homework assignment, 4: Laboratory exercise/exam, 5: Seminar / presentation, 6: Term paper), LO : Learning Outcome | | |
| The properties of gases: the states of gases, the gas laws, ideal gases, kinetic theory.The first Law : basic concepts, work, heat and energy, internal energy, expansion work, enthalpy, The Second law: entropy, dispersal of energy, entropy changes accompanying specific process. The third law of thermodynamics. Gibbs energy. Chemical equilibrium, description of equilibrium, equilibrium constant. Physical transformations of pure substances.Phase diagrams, the stabilities of phases, phase boundaries, thermodynamic criterion of equilibrium, surface tension, capillary action Simple mixtures: partial molar quantities, the thermodynamic of mixing, the chemical potentials of liquids, liquid mixtures, colligative properties.The rates of chemical reactions: experimental techniques, the rate of reactions, integrated rate laws, elementary reactions, consecutive elementary reactions, unimolecular reactions. Molecular reaction dynamics: collision theory, diffusion-controlled reactions reactions, Activated complex theory, the Eyring equation, thermodynamic aspects, Adsorption, physical and chemical adsorpsion, adsorption isotherms. Adsorption and catalysis.
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| Course Syllabus | | Week | Subject | Related Notes / Files | | Week 1 | The properties of gases: the states of gases, the gas laws, ideal gases, kinetic theory | | | Week 2 | The first Law : basic concepts, work, heat and energy, internal energy, expansion work, enthalpy | | | Week 3 | The Second law: entropy, dispersal of energy, entropy changes accompanying specific process.
| | | Week 4 | The third law of thermodynamics. Gibbs energy | | | Week 5 | Chemical equilibrium, description of equilibrium, equilibrium constant. | | | Week 6 | Physical transformations of pure substances. Phase diagrams, the stabilities of phases, phase boundaries, thermodynamic criterion of equilibrium, surface tension, capillary action. | | | Week 7 | Simple mixtures: partial molar quantities, the thermodynamic of mixing, the chemical potentials of liquids, liquid mixtures, colligative properties
| | | Week 8 | Mid-term exam | | | Week 9 | The rates of chemical reactions: experimental techniques, the rate of reactions, integrated rate laws, | | | Week 10 | Elementary reactions, consecutive elementary reactions, unimolecular reactions. | | | Week 11 | Molecular reaction dynamics: collision theory, diffusion-controlled reactions reactions, | | | Week 12 | Molecular collision dynamics | | | Week 13 | II midterm exam. | | | Week 14 | Activated complex theory, the Eyring equation, thermodynamic aspects,
| | | Week 15 | Adsorption, physical and chemical adsorpsion, adsorption isotherms. Adsorption and catalysis.
| | | Week 16 | End-of-term exam | | | |
| 1 | Atkıns, P. W. 2001; Fizikokimya, Bilim Yayıncılık , Ankara . | | | |
| Method of Assessment | | Type of assessment | Week No | Date | Duration (hours) | Weight (%) | | Mid-term exam | 9 | 08.04.2014 | 1,5 | 50 | | End-of-term exam | 17 | 07.06.2014 | 1.5 | 50 | | |
| Student Work Load and its Distribution | | Type of work | Duration (hours pw) | No of weeks / Number of activity | Hours in total per term | | Yüz yüze eğitim | 3 | 14 | 42 | | Sınıf dışı çalışma | 3 | 3 | 9 | | Arasınav için hazırlık | 8 | 2 | 16 | | Arasınav | 1.5 | 2 | 3 | | Kısa sınav | 2 | 1 | 2 | | Dönem sonu sınavı için hazırlık | 13 | 2 | 26 | | Dönem sonu sınavı | 2 | 1 | 2 | | Total work load | | | 100 |
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